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V-ray Material Library for 3ds max 
Info
File format: .mat
Size: 282MB
Architectural (150mb)
Automotive (12mb)
Cloth (58mb)
Food (12mb)
Glass (12mb)
Liquid (12mb)
Metal (94mb)
Organic (195mb)
Other (28mb)
Plastics (22mb)
SpecialEffects (9mb)
SSS (1mb)
Stone (30mb)
Transparent (6mb)
Unrealistic (1mb)
VRay 1.5 (6mb)
Vray fur (9mb)
Wood (140mb)
RapidShare Download links for 3ds max v-ray material
http://rapidshare.com/files/140063911/Vray_Materials.part1.rar
http://rapidshare.com/files/140064010/Vray_Materials.part2.rar
http://rapidshare.com/files/140063981/Vray_Materials.part3.rar